Feasibility of a Full Chalcopyrite Tandem Solar Cell: A Quantitative Numerical Approach

The potential of tandem solar cells combining two chalcopyrite absorbers is evaluated using numerical modeling based on an exhaustive set of experimental parameters, offering a high degree of confidence in the numerical values reported herein. The simple yet reliable approach used here combines a transfer matrix-based optical model of the wide bandgap CIGSe top subcell used as input for the 1D electrical modeling of a reference narrow bandgap CIGSe bottom cell. Various optical optimizations to the top subcell are investigated, with the aim to increase the bottom subcell current and reduce the efficiency threshold needed at the top subcell for the tandem device to beat the current single junction efficiency record. The results here suggest that significant progress compared with the state of the art can be made using a pure CuGaSe2 absorber combined with an optimized back contact with an ultrathin transition metal oxide interlayer. With a bottom subcell current more than doubled in the optimum top subcell configuration, a challenging yet clear pathway for the future realization of tandem solar cells based on chalcopyrite absorbers is offered.

Automated summary

The potential of tandem solar cells combining two chalcopyrite absorbers was evaluated using numerical modeling and optical optimizations, suggesting significant progress can be made by utilizing a pure CuGaSe2 absorber with an optimized back contact containing an ultrathin transition metal oxide interlayer. By doubling the bottom subcell current in the optimum top subcell configuration, a challenging yet clear pathway for the future realization of tandem solar cells based on chalcopyrite absorbers is offered.