4.7 Review

S-Scheme Photocatalytic Systems

Journal

SOLAR RRL
Volume 5, Issue 7, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/solr.202100118

Keywords

band bending; Fermi level difference; internal electric field; solar energy conversion; S-scheme photocatalysts

Funding

  1. National Natural Science Foundation of China [21871155, 51972177]
  2. Natural Science Foundation of Ningbo City [2018A610067, 2019A610022]
  3. Ningbo University [SJLY2021010]
  4. Fan 3315 Plan
  5. Yongjiang Scholar Plan

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The development history, advantages, applications, challenges and outlook of S-scheme photocatalysts have been summarized and discussed in this article, providing insights for utilizing their potential in renewable energy generation and environmental remediation.
Recently, step-scheme (S-scheme) photocatalysts have received widespread attention in the field of solar fuel development and transformation because of efficient charge spatial separation along with strong redox capabilities. Herein, the development history of S-scheme photocatalysts is summarized and reviewed, from Z-scheme photocatalysts to S-scheme photocatalysts. Advantages of S-scheme photocatalysts are also discussed in depth and detail, including design principles and construction strategies as well as charge transfer mechanisms. In addition, identification characterizations for S-scheme photocatalysts and their solar energy conversion applications are also reviewed. Finally, conclusions and outlooks for solar energy conversion challenges are demonstrated. It provides insights and up-to-date information to enable the scientific community to fully tap into the potential of S-scheme photocatalysts in renewable energy generation and environmental remediation.

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