Cellulose Isolated From Waste Rubber Wood and Its Application in PLA Based Composite Films

Waste rubber wood (RW) is the castoff of rubber plantation with abundant reservation but without high-value utilization. In this study, cellulose with high purity has been efficiently isolated from waste RW and further processed into cellulose nanocrystals. By means of acetylation, more hydrophobic cellulose-based products, namely acetylated rubber wood cellulose (Ac-RWC) and acetylated rubber wood cellulose nanocrystals (Ac-RW-CNC) had been attempted as reinforcing fillers for fabricating two series of PLA-based composite films via spin coating instead of currently prevailing melt compounding technique. To ensure a uniformed dispersion of fillers in PLA matrix, the addition of reinforcing filler should be equal to or less than 5% based on the film dry weight. Compared with pure PLA film, the Ac-RWC reinforced PLA composite films are more thermally stable, while the Ac-RW-CNC reinforced PLA composite films on the other hand exhibit more enhanced performance in mechanical properties and the degree of crystallinity. The highest tensile strength (55.0 MPa) and Young's modulus (3.9 GPa) were achieved for 5%Ac-RW-CNC/PLA composite film.

Automated summary

The study focuses on isolating cellulose nanocrystals from waste rubber wood and using them as reinforcing fillers in PLA composite films. Adding reinforcing fillers at a level equal to or less than 5% by weight significantly improves the mechanical properties and crystallinity of the composite films.