Journal
EUROPEAN POLYMER JOURNAL
Volume 84, Issue -, Pages 837-848Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2016.04.022
Keywords
Renewable chemicals; AB-type monomers; Thermoplastic polyurethane/polyurea; Non-isocyanate synthesis; Thiol-ene addition
Categories
Funding
- MICINN (Ministerio de Ciencia e Innovacion) [MAT2014-53652-R]
- HENKEL AG & Co. KGaA, Adhesive Technologies
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Polyurethanes and polyureas from renewable castor oil-derived 10-undecenoic acid were synthesized using the AB-type self-condensation approach. omega-Hydroxy- or omega-amino methyl carbamate ester precursor monomers were prepared under mild conditions from cysteamine methyl carbamate by thiol-ene addition. Synthesis of cysteamine carbamate and the self-condensable monomers derived of 10-unclecenol or 10-undecenylamine was studied by using different synthetic conditions. Two different polymers, a polyurethane and a polyurea, were prepared using conventional catalysts thus following a non-isocyanate route. The proposed synthetic approach constitutes a general route that allows for the easy preparation of methyl carbamate monomers not only from renewable (limonene, myrcene, geraniol, etc.), but also from petroleum-derived unsaturated substrates. (C) 2016 Elsevier Ltd. All rights reserved.
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