Journal
EUROPEAN POLYMER JOURNAL
Volume 78, Issue -, Pages 46-60Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2016.03.003
Keywords
Soybean oil; Thiol-ene reaction; Polyol; Thermoplastic polyurethane; Elastomer; Shape memory
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Funding
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education [2015R1D1A1A09061172]
- Fusion Research Program for Green Technologies through the NRF - Ministry of Science, ICT and Future Planning [2012M3C1A1054503]
- National Research Foundation of Korea [2012M3C1A1054503, 22A20130012822] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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Growing concerns over long-term environmental and waste management issues direct the use of renewable resources for sustainable polymers in the polymer industry. In this study, controlled preparations of vegetable oil-based polyols with predetermined primary hydroxyl functionalities ranging from 2 to 4 were attempted using a one-step thiol-ene click reaction between soybean oil (SO) and 2-mercaptoethanol (ME). The numbers of the primary hydroxyl functionalities in the SO-based polyols could be easily controlled by terminating the thiol-ene reaction at a particular reaction time and conversion of the carbon-carbon double bonds of SOs. The SO-based polyols were a mixture of SO molecules with different numbers of ME units, where the SO molecules with three and four ME units afforded thermoplastic polyurethanes (TPUs) with hyperbranched architectures. The TPUs exhibited increased glass transition temperature, moduli and tensile strength values, demonstrating that they were hard and tough elastomers. Relatively low tension set values, along with high elongation at break and low hysteresis values demonstrated the good elastomeric characteristics of the TPUs. The TPUs also exhibited excellent shape memory properties and film transparencies because of their hyperbranched architectures. This study demonstrates an efficient and controlled synthetic pathway for the preparation of unique polyols and polymers from renewable resources, enabling new applications of eco-friendly materials in high value-added technologies. (C) 2016 Elsevier Ltd. All rights reserved.
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