Iridium Oxide Modified with Silver Single Atom for Boosting Oxygen Evolution Reaction in Acidic Media

Electrocatalytic oxygen evolution in acidic media is crucial for promoting water splitting. Herein, we report an Ag-1/IrOx single atom catalyst (SAC) with Ag single atoms embedded in an IrO2 matrix obtained through the oxidation of IrAg single atom alloy (SAA). The Ag-1/IrOx SAC delivers a low overpotential of 224 mV at current density of 10 mA cm(-2) and a long-term durability better than that of commercial Ir (C-Ir). DFT calculation indicates that six Ir atoms neighboring the single Ag atom exhibit a higher-valence Irx+ (x > 4) and thus lower the adsorption free energy significantly to boost the oxygen evolution process. Furthermore, the strong Ir-O bonds and low overpotential prevent the loss of the lattice oxygen in the Ag-1/IrOx SAC, resulting in high oxygen evolution reaction stability.

Automated summary

An Ag-1/IrOx single atom catalyst with embedded Ag single atoms in an IrO2 matrix is reported for efficient oxygen evolution in acidic media. DFT calculations show that the neighboring Ir atoms to the single Ag atom assist in boosting the oxygen evolution process. Strong Ir-O bonds and low overpotential in the Ag-1/IrOx SAC prevent lattice oxygen loss, resulting in high oxygen evolution reaction stability.