Journal
EUROPEAN POLYMER JOURNAL
Volume 84, Issue -, Pages 173-187Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.eurpolymj.2016.09.019
Keywords
Polylactide; Cellulose nanocrystal; Ring opening polymerization; Grafting; Viscoelastic properties
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The effects of polylactide-graft-cellulose nanocrystals on the thermal and mechanical properties of poly(l-lactide) matrices were investigated. Cellulose nanocrystals (CNCs) were grafted with polylactide chains via a solvent-free process by ring-opening polymerization of 1-lactide using magnesium hydride as a catalyst. The efficiency of grafting was determined by infra-red, X-ray photoelectron spectroscopy and nuclear magnetic resonance analyses. X-ray diffraction analyses showed that the crystalline nature of the CNCs was preserved. Nanocomposites based on poly(l-lactide) matrix containing ungrafted nanocrystals (PLLA/CNCs) and grafted nanocrystals (PLLA/PLLA-g-CNCs) were investigated. DSC revealed that the grafted nanocrystals exhibited a strong influence on the crystallinity of the nanocomposites, inducing a significant enhancement of the mechanical properties of PLLA/PLLA-g-CNCs compared with PLLA/CNCs material. The role played by the polylactide grafted layer on the interaction between the CNCs and PLLA matrix was revealed by mechanical analyses in the solid and molten states. (C) 2016 Elsevier Ltd. All rights reserved.
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