4.2 Article

Structural properties and adsorption of uranyl ions on the nanocomposite hydroxyapatite/white clay

Journal

APPLIED NANOSCIENCE
Volume 12, Issue 4, Pages 1101-1111

Publisher

SPRINGER HEIDELBERG
DOI: 10.1007/s13204-021-01790-y

Keywords

Nanocomposite hydroxyapatite; white clay; Uranyl ions; Adsorption

Funding

  1. National Science Centre (Poland) [2017/01/X/ST4/01939]

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The research focuses on the problem of uranium expansion in the environment and the potential use of clay and nanocomposite clay/Hap for uranium removal. The study shows that nanocrystalline composites Hap/white clay can be effective adsorbent for the removal of uranyl ions, with adsorption dependent on temperature and pH of the solution.
Uranium is more and more extensively applied as a source of energy and can be potentially used for nuclear weapon production. Owing to that fact, the problem of uranium expansion in the environment is the object of research and draw attention many scientists. One of the most effective methods of uranium removal from the wastewater (where uranium is present in a low concentration and occurs mainly in the form of uranyl ion, UO22+) is the adsorbent usage. It is important to discover an adsorbent which will be effective, widely available and cheap. The paper discusses properties and the ability of U (VI) adsorption on a clay and nanocomposite clay/Hap (hydroxyapatite) obtained by wet method. The adsorbents were characterized by the mentioned below tests: XRD, XRF, the porosity (nitrogen adsorption-desorption method), zeta potential, surface charge density and sorption of U (VI). It was shown that nanocrystalline composites Hap/white clay can be appropriate adsorbent for removal of uranyl ions. The adsorption depends on the temperature and pH of the solution.

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