4.7 Article

Organic/inorganic hybrid nanostructures of polycrystalline perylene diimide decorated ZnO nanorods highly enhanced dual sensing performance of UV light/CO gas sensors

Journal

RESULTS IN PHYSICS
Volume 24, Issue -, Pages -

Publisher

ELSEVIER
DOI: 10.1016/j.rinp.2021.104173

Keywords

Multi-crystalline preylene diimide; PDI-C10C12PF7; ZnO nanorods; UV light sensor; CO gas sensor; Dual sensing

Funding

  1. Center for the Semiconductor Technology Research from The Featured Areas Research Center Program within the framework of the Higher Education Sprout Project by the Ministry of Education (MOE) in Taiwan
  2. Ministry of Science and Technology (MOST), Taiwan [MOST 107-2221-E-260-015-MY3, MOST 105-2119-M260-005-MY3, MOST 109-2634-F-009-029]
  3. National Chi Nan University

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Dual light-detecting/gas-sensing devices based on organic/inorganic hybrid nanostructures were fabricated and characterized using various material analysis techniques. The results demonstrate that the hybrid nanostructure can effectively enhance UV light and CO gas dual-sensing properties, making it promising for future portable hazardous light and gas sensing applications.
Organic/inorganic hybrid nanostructures-based dual light-detecting/gas-sensing devices were fabricated. In this research, polycrystalline perylene diimide (PDI) membrane was coated on ZnO nanorods (NRs), functioning as sensing nanocomposites. Multiple material analyses including scanning electron microscope (SEM), energy dispersive spectrometer (EDS), high resolution transmission electron microscopy (HR-TEM), X-ray diffractometer (XRD), Raman spectroscopy, and confocal laser scanning microscopy (CLSM) indicate that organic perylene diimide was successfully deposited on ZnO NRs, forming organic/inorganic membrane on the sensing device. To examine the influence of organic/inorganic hybrid nanostructure on photo-sensing and gas-sensing behaviors, UV light detection and CO gas sensing impulse response were measured. Results reveal that organic/inorganic hybrid nanostructure can effectively enhance UV light and CO gas dual-sensing properties with addition of PDI. The coating of organic PDI on the ZnO NRs not only improves the gas interaction capability and gas-sensing stability but also enhances the UV absorption efficiency. Owing to advantages of low cost, simple fabrication, compact size, and device stability, hybrid PDI/ZnO organic/inorganic light/gas dual-sensing devices are promising for future portable hazardous light and gas sensing applications.

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