Journal
EUROPEAN PHYSICAL JOURNAL D
Volume 70, Issue 5, Pages -Publisher
SPRINGER
DOI: 10.1140/epjd/e2016-70153-2
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Funding
- Swiss National Science Foundation [200020-144367/1]
- Fonds der Chemischen Industrie
- DFG [SFB 813]
- EPSRC
- ARCHER project [eCSE01-013]
- COST Action [CM1301 CELINA]
- EPSRC [EP/G055599/1] Funding Source: UKRI
- Swiss National Science Foundation (SNF) [200020_144367] Funding Source: Swiss National Science Foundation (SNF)
- Engineering and Physical Sciences Research Council [EP/G055599/1] Funding Source: researchfish
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The article briefly reviews three subjects recently investigated in Fribourg: (i) electron collisions with surfaces of ionic liquids, (ii) two-dimensional (2D) electron energy loss spectra and (iii) resonances in absolute cross sections for electronic excitation of unsaturated compounds. Electron energy loss spectra of four ionic liquids revealed a number of excited states, including triplet states. A solution of a dye in an ionic liquid showed an energy-loss band of the solute, but not in all ionic liquids. 2D spectra reveal state-to-state information (given resonance to given final state) and are shown to be an interesting means to gain insight into dynamics of nuclear motion in resonances. Absolute cross sections for pyrimidine are reported as a function of scattering angle and as a function of electron energy. They reveal resonant structure which was reproduced very nicely by R-matrix calculations. The calculation provided an assignment of the resonances which reveals common patterns in compounds containing double bonds.
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