4.7 Review

Graphene/Reduced Graphene Oxide-Carbon Nanotubes Composite Electrodes: From Capacitive to Battery-Type Behaviour

Journal

NANOMATERIALS
Volume 11, Issue 5, Pages -

Publisher

MDPI
DOI: 10.3390/nano11051240

Keywords

energy storage; multifunctional materials; composites; graphene; nanostructures

Funding

  1. FCT-Fundacao para a Ciencia e a Tecnologia [57/2016, UID/EMS/00481/2019, UIDB/50011/2020, UIDP/50011/2020]
  2. Centro 2020, through the European Regional Development Fund (ERDF) [CENTRO-01-0145-FEDER-022083]
  3. Fundação para a Ciência e a Tecnologia [UID/EMS/00481/2019] Funding Source: FCT

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This review surveys recent achievements in the development of supercapacitors (SC) based on composites of carbon-derived materials, discussing factors influencing specific capacitance and overviewing specific energy, power, and cycling stability of SC with composite electrode materials.
Thanks to the advanced technologies for energy generation such as solar cells and thermo- or piezo-generators the amount of electricity transformed from light, heat or mechanical pressure sources can be significantly enhanced. However, there is still a demand for effective storage devices to conserve electrical energy which addresses the wide range of large stationary applications from electric vehicles to small portable devices. Among the large variety of energy-storage systems available today, electrochemical energy sources and, in particular, supercapacitors (SC), are rather promising in terms of cost, scaling, power management, life cycle and safety. Therefore, this review surveys recent achievements in the development of SC based on composites of such carbon-derived materials as graphene (G) and reduced graphene oxide (rGO) with carbon nanotubes (CNT). Various factors influencing the specific capacitance are discussed, while specific energy and power as well as cycling stability of SC with G/rGO-CNT composite electrode materials are overviewed.

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