Journal
CATALYSTS
Volume 11, Issue 4, Pages -Publisher
MDPI
DOI: 10.3390/catal11040435
Keywords
supercritical fluids; biodiesel; continuous flow reactor; transesterification
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Funding
- Wayne and Gayle Laufer Foundation
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This study explores the non-catalyzed supercritical methanol process for continuous biodiesel production, showing that higher temperatures and pressures result in increased methyl-ester yield. The use of a new reactor technology can reduce setup costs and improve yields, while also studying the kinetics of the transesterification process under different conditions in supercritical methanol.
This work investigates the non-catalyzed supercritical methanol (SCM) process for continuous biodiesel production. The lab-scale setup was designed and used for biodiesel production in the temperature range of 520-650 K and 83-380 bar with an oil-to-methanol molar ratio ranging from 1:5 to 1:45. The experiments were performed in the coiled plug flow tubular reactor. The volumetric flow rate of the methanol/oil ranged from 0.1-10 mL/min. This work examines a new reactor technology involving preheating and pre-mixing of the methanol/oil mixture to reduce setup cost and increase biodiesel yield under the same reaction conditions. Work performed showed that FAME's yield increased rapidly with temperature and pressure above the methanol critical points (i.e., 513 K and 79.5 bar). The best methyl-ester yield using this reaction technology was 91% at 590 K temperature and 351 bars with an oil-to-methanol ratio of 39 and a 15-min residence time. Furthermore, the kinetics of the free catalyst transesterification process was studied in supercritical methanol under different reaction conditions.
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