Journal
ADVANCED OPTICAL MATERIALS
Volume 9, Issue 13, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adom.202002251
Keywords
crystals; fluorescence; luminescence; materials science; organic molecules
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Funding
- Spanish Ministerio de Economia y Competitividad (MINECO-FEDER) [CTQ2017-87054]
- Centers of Excellence in R&D program of the MINECO [SEV-2016-0686]
- Campus of International Excellence (CEI) UAM+CSIC
- NRF - Ministry of Science, ICT and Future Planning [2017R1E1A1A01075372]
- Fundamental Research Funds for the Central Universities
- Northwestern Polytechnical University [D5000200574]
- project of optional research topic in the Institute of Flexible Electronics [2020QY07]
- National Natural Science Foundation of China [D5110200516]
- Technical Research Centre, IACS [AI/1/62/IACS/2015]
- Ramon y Cajal grant of the MINECO [RYC-2015-19234]
- Chinese Scholarship Council (CSC)
- National Research Foundation of Korea [4120200513611, 2017R1E1A1A01075372] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
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This work carefully examines all intramolecular and intermolecular factors affecting radiative and nonradiative processes in crystalline all-organic molecular solids, starting from molecular properties, to provide guidelines for targeted molecular materials design.
Luminescent small, all-organic molecules are of tremendous interest in materials and life science applications. Nevertheless, targeted design requires a basic understanding of the excited state deactivation pathways of the molecules themselves, and the modulations of the processes that occur in the solid state. This particularly concerns crystalline molecular solids, as here not only solid-state rigidification contributes to these modulations, but specific intermolecular interactions as well. Starting from the molecular properties, this work carefully disentangles all intramolecular and intermolecular factors to the radiative and nonradiative processes in crystalline all-organic molecular solids to provide guidelines for targeted molecular materials design.
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