Journal
WATER
Volume 13, Issue 6, Pages -Publisher
MDPI
DOI: 10.3390/w13060779
Keywords
volume averaging; closure formulation; porous media; adsorption; arsenic filtration
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Funding
- University of Wisconsin-Milwaukee in the USA
- IIT (BHU) in India
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The process of transport and trapping of arsenic ions in porous water filters is treated as a classic mass transport problem, with modeling conducted using the convection-diffusion equation at the pore scale. The upscaling reveals two possible forms of macroscopic equations for predicting arsenic concentrations in the filters, with the introduction of an additional transport coefficient known as the adsorption-induced vector being a key finding. This theoretical effort represents the first detailed micro-macro coupling in modeling the transport of arsenic species in water filters.
The process of transport and trapping of arsenic ions in porous water filters is treated as a classic mass transport problem which, at the pore scale, is modeled using the traditional convection-diffusion equation, representing the migration of species present in very small (tracer) amounts in water. The upscaling, conducted using the volume averaging method, reveals the presence of two possible forms of the macroscopic equations for predicting arsenic concentrations in the filters. One is the classic convection-dispersion equation with the total dispersion tensor as its main transport coefficient, and which is obtained from a closure formulation similar to that of the passive diffusion problem. The other equation form includes an additional transport coefficient, hitherto ignored in the literature and identified here as the adsorption-induced vector. These two coefficients in the latter form are determined from a system of two closure problems that include the effects of both the passive diffusion as well as the adsorption of arsenic by the solid phase of the filter. This theoretical effort represents the first serious effort to introduce a detailed micro-macro coupling while modeling the transport of arsenic species in water filters representing homogeneous porous media.
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