Journal
POLYMERS
Volume 13, Issue 7, Pages -Publisher
MDPI
DOI: 10.3390/polym13071139
Keywords
de-vulcanization; recycling; passenger car tire; sustainability; twin-screw extruder
Categories
Funding
- Netherlands Organization for Scientific Research (NWO) [023.004.127]
- Tech for Future (TFF) Centre of Expertise of applied High Tech Systems and Materials (HTSM) Oost, a cooperation of the province of Overijssel
- University of Applied Sciences Windesheim and Saxion
- University of Twente, Enschede, The Netherlands
- Schill+Seilacher Struktol GmbH, Hamburg, Deutschland
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The de-vulcanization of rubber using a twin-screw extruder and DBD as the agent shows promise for reusing rubber materials. However, adjustments to the process were necessary due to the high melting point of DBD. This method improved the coherence and tensile properties of the devulcanizate after vulcanization.
De-vulcanization of rubber has been shown to be a viable process to reuse this valuable material. The purpose of the de-vulcanization is to release the crosslinked nature of the highly elastic tire rubber granulate. For present day passenger car tires containing the synthetic rubbers Styrene-Butadiene Rubber (SBR) and Butadiene Rubber (BR) and a high amount of silica as reinforcing filler, producing high quality devulcanizate is a major challenge. In previous research a thermo-chemical mechanical approach was developed, using a twin-screw extruder and diphenyldisulfide (DPDS) as de-vulcanization agent.The screw configuration was designed for low shear in order to protect the polymers from chain scission, or uncontrolled spontaneuous recombination which is the largest problem involved in de-vulcanization of passenger car tire rubber. Because of disadvantages of DPDS for commercial use, 2-2 '-dibenzamidodiphenyldisulfide (DBD) was used in the present study. Due to its high melting point of 140 degrees C the twin-screw extruder process needed to be redesigned. Subsequent milling of the devulcanizate at 60 degrees C with a narrow gap-width between the mill rolls greatly improved the quality of the devulcanizate in terms of coherence and tensile properties after renewed vulcanization. As the composition of passenger car tire granulate is very complex, the usefulness of the Horikx-Verbruggen analysis as optimization parameter for the de-vulcanization process was limited. Instead, stress-strain properties of re-vulcanized de-vulcanizates were used. The capacity of the twin-screw extruder was limited by the required residence time, implying a low screw speed. A best tensile strength of 8 MPa at a strain at break of 160% of the unblended renewed vulcanizate was found under optimal conditions.
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