Journal
POLYMERS
Volume 13, Issue 10, Pages -Publisher
MDPI
DOI: 10.3390/polym13101614
Keywords
polyanion; dense 1; 2; 3-traizole polymer; copper(I)-catalyzed azide– alkyne cycloaddition polymerization; metal ion adsorption
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Funding
- JSPS Kakenhi [JP26288061]
- Sasakawa Scientific Research Grant from The Japan Science Society [2020-3009]
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In this study, a new polyanion poly(AH) with a dense 1,2,3-triazole backbone was successfully synthesized and found to be well soluble in water under basic conditions. Poly(AH) showed weaker anionic properties compared to polyacrylic acid and exhibited a high adsorption preference for Fe3+ ions among the metal ions tested.
Polyanions are an important class of water-soluble polymers because polyanions are utilized in a wide range of industrial fields. It is thus a great challenge to develop polyanions with novel structures to make their applications broader. In this study, a new polyanion with a dense 1,2,3-triazole backbone, poly(4-azido-5-hexanoic acid) (poly(AH)), was synthesized by copper(I)-catalyzed azide-alkyne cycloaddition (CuAAC) polymerization of t-butyl 4-azido-5-hexanoate followed by hydrolysis of the t-butyl ester groups. Turbidimetric and potentiometric titration data indicated that poly(AH) was well soluble in water under basic conditions (pH < 7) and a weaker polyanion (apparent pK(a) = 5.4) than polyacrylic acid (apparent pK(a) = 4.5). Adsorption tests exhibited that sodium salt of poly(AH) (poly(AH)Na) adsorbed most preferably Fe3+ among the four metal ions examined, i.e., Cu2+, Pb2+, Li+, and Fe3+. H-1 spin-lattice relaxation time measurements indicated that Fe3+ ions were adsorbed favorably onto the 1,2,3-triazole residues.
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