4.6 Article

Modern Biodegradable Plastics-Processing and Properties Part II

Journal

MATERIALS
Volume 14, Issue 10, Pages -

Publisher

MDPI
DOI: 10.3390/ma14102523

Keywords

processing of plastics; mechanical properties; blown film; optical properties; barrier properties; starch; polylactide; polyethylene

Funding

  1. project Lublin University of Technology-Regional Excellence Initiative - Polish Ministry of Science and Higher Education [030/RID/2018/19]

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This study tested four different plastics and found that biodegradable plastics have comparable or even better mechanical strength than petrochemical plastics, and the influence of screw rotational speed on mechanical characteristics, as well as the decrease in barrier properties with increased speed, was demonstrated. Additionally, it was indicated that biodegradable plastics may be competitive with conventional petrochemical materials in certain niche applications.
Four different plastics were tested: potato starch based plastic (TPS-P)-BIOPLAST GF 106/02; corn starch based plastic (TPS-C)-BioComp BF 01HP; polylactic acid (polylactide) plastic (PLA)-BioComp BF 7210 and low density polyethylene, trade name Malen E FABS 23-D022; as a petrochemical reference sample. Using the blown film extrusion method and various screw rotational speeds, films were obtained and tested, as a result of which the following were determined: breaking stress, strain at break, static and dynamic friction coefficient of film in longitudinal and transverse direction, puncture resistance and strain at break, color, brightness and gloss of film, surface roughness, barrier properties and microstructure. The biodegradable plastics tested are characterized by comparable or even better mechanical strength than petrochemical polyethylene for the range of film blowing processing parameters used here. The effect of the screw rotational speed on the mechanical characteristics of the films obtained was also demonstrated. With the increase in the screw rotational speed, the decrease of barrier properties was also observed. No correlation between roughness and permeability of gases and water vapor was shown. It was indicated that biodegradable plastics might be competitive for conventional petrochemical materials used in film blowing niche applications where cost, recyclability, optical and water vapor barrier properties are not critical.

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