Journal
ADVANCED ENERGY MATERIALS
Volume 11, Issue 17, Pages -Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202100157
Keywords
cobalt boride; heterointerfaces; oxygen reduction reaction; zinc– air batteries
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Funding
- Ministry of Education in Singapore [RG118/18, RG105/19]
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Compositional and structural engineering of metal-metalloid materials can enhance their electrocatalytic performance, with heterointerfaces between N-doped carbon and cobalt boride nanosheets yielding efficient and stable systems for the oxygen reduction reaction. The best-performing electrocatalyst exhibits significant advantages compared to commercial Pt/C, making it suitable for assembling zinc-air batteries.
Compositional and structural engineering of metal-metalloid materials can boost their electrocatalytic performance. Herein, a highly efficient and stable electrocatalytic system for the oxygen reduction reaction is obtained by creating heterointerfaces between N-doped carbon and cobalt boride nanosheets. Furthermore, a detailed investigation on the effect of annealing temperature as well as the amount of carbon and nitrogen sources is conducted to tune their performance. The best electrocatalyst among the prepared materials is found to have an onset potential of 1.05 V and half-wave potential of 0.94 V, which are 40 and 72 mV positive in comparison to commercial Pt/C, respectively. Finally, a zinc-air battery is also assembled using the catalyst.
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