Phosphate recovery as vivianite using a flow-electrode capacitive desalination (FCDI) and fluidized bed crystallization (FBC) coupled system

It is critical to both effectively remove and recover phosphate (P) from wastewater given the wide-ranging environmental (i.e., preventing eutrophication and restoring water quality) and economic (i.e., overcoming P resource scarcity) benefits. More recently, considerable academic effort has been devoted towards harvesting P as vivianite, which can be used as a potential slow-release fertilizer and possible reagent for the manufacture of lithium iron phosphate (LiFePO4), the precursor in fabricating Li-ion secondary batteries. In this study, we propose an innovative P recovery process, in which P is first preconcentrated via a flow-electrode capacitive deionization (FCDI) device followed by immobilization as vivianite crystals in a fluidized bed crystallization (FBC) column. The effects of different operational parameters on FCDI P preconcentration performance and energy consumption are investigated. Results show that 63% of P can be removed and concentrated in the flow-electrode chamber with a reasonable energy requirement under optimal operating conditions. The FBC system resulted in immobilization of similar to 80% of P as triangular or quadrangular pellets, which were verified to be high-purity vivianite crystals by scanning electron microscopy with energy dispersive X-ray spectroscopy (SEM-EDX) and extended X-ray absorption fine structure (EXAFS) spectroscopy. This study provides a pathway for efficient recovery of P as a value-added product (i.e., vivianite) from P-rich wastewaters. (c) 2021 Elsevier Ltd. All rights reserved.

Automated summary

Efficient removal and recovery of phosphate from wastewater is crucial for environmental and economic benefits. Recent efforts have focused on harvesting phosphate as vivianite, a potential slow-release fertilizer and precursor for lithium iron phosphate production. A novel process involving flow-electrode capacitive deionization (FCDI) and fluidized bed crystallization (FBC) has shown promising results in P concentration and immobilization. The study provides a pathway for sustainable phosphorus recovery from rich wastewaters.