4.4 Article

Synthetic studies towards (±)-isopalhinine A: Preparation of the bicyclic core via Nazarov cyclization

Journal

TETRAHEDRON LETTERS
Volume 74, Issue -, Pages -

Publisher

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2021.153177

Keywords

Isopalhinine A; Total synthesis; Nazarov cyclization; Bicycle; Lycopodium alkaloid

Funding

  1. Baylor University
  2. Welch Foundation [AA-006]
  3. Cancer Prevention and Research Institute of Texas (CPRIT) [R1309]
  4. NSF [CHE-1764240]

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This manuscript discusses progress in the total synthesis of (+/-)-isopalhinine A, focusing on an allene ether Nazarov cyclization reaction to generate the bicyclic core.
This manuscript describes progress towards the total synthesis of (+/-)-isopalhinine A wherein an allene ether Nazarov cyclization gives rise to the bicyclic core. (C) 2021 Elsevier Ltd. All rights reserved.

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