Journal
SYNLETT
Volume 32, Issue 12, Pages 1219-1222Publisher
GEORG THIEME VERLAG KG
DOI: 10.1055/a-1469-5742
Keywords
iron catalysis; carbazates; hydrazinecarboxylates; alkoxycarbonylation; benzimidazoisoquinolinones; alkenes
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Funding
- Hunan Provincial Natural Science Foundation of China [2020JJ5390, 2020JJ4445]
- Scientific Research Fund of Hunan Provincial Education Department [19C1254, 19B390]
- Technology Innovation and Development Guidance Program of Chang De [2020ZD16]
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A FeCl2·4H2O-catalyzed oxidative alkoxycarbonylation of activated alkenes with carbazates has been developed, leading to structurally diverse benzimidazo[2,1-a]isoquinolin-6(5H)-one frameworks in moderate to good yield.
A FeCl2 center dot 4H(2)O-catalyzed oxidative alkoxycarbonylation of activated alkenes with carbazates toward alkoxycarbonylated benzimidazo[2,1-a]isoquinolin-6(5H)-ones has been established. The reaction proceeded smoothly to furnish a series of structurally diverse benzimidazo[2,1-a]isoquinolin-6(5H)-one frameworks in moderate to good yield.
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