4.8 Article

Nanostructured Carbon Electrocatalysts for Energy Conversions

Journal

SMALL
Volume 17, Issue 48, Pages -

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202007136

Keywords

electrocatalysis; electrocatalyst; energy conversion; heteroatom‐ doped carbon nanomaterial; nanostructured carbon

Funding

  1. US National Science Foundation [NSF DMR-1508611]
  2. Shenzhen Polytechnic

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The growing energy demand worldwide has led to increased use of fossil fuels, which is depleting faster and causing more negative environmental impacts. Alternative, environmentally friendly energy sources such as fuel cells and electrolyzers are being developed. Significant progress has been made in this area, though challenges remain in scaling up such energy systems due to their noble metal catalysts.
The growing energy demand worldwide has led to increased use of fossil fuels. This, in turn, is making fossil fuels dwindle faster and cause more negative environmental impacts. Thus, alternative, environmentally friendly energy sources such as fuel cells and electrolyzers are being developed. While significant progress has already been made in this area, such energy systems are still hard to scale up because of their noble metal catalysts. In this concept paper, first, various scalable nanocarbon-based electrocatalysts that are being synthesized for energy conversions in these energy systems are introduced. Next, notable heteroatom-doping and nanostructuring strategies that are applied to produce different nanostructured carbon materials with high electrocatalytic activities for energy conversions are discussed. The concepts used to develop such materials with different structures and large density of dopant-based catalytic functional groups in a sustainable way, and the challenges therein, are emphasized in the discussions. The discussions also include the importance of various analytical, theoretical, and computational methods to probe the relationships between the compositions, structures, dopants, and active catalytic sites in such materials. These studies, coupled with experimental studies, can further guide innovative synthetic routes to efficient nanostructured carbon electrocatalysts for practical, large-scale energy conversion applications.

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