Journal
PROGRESS IN PHOTOVOLTAICS
Volume 29, Issue 6, Pages 630-637Publisher
WILEY
DOI: 10.1002/pip.3413
Keywords
back interface recombination; Ga back grading; TRPL lifetime; V-OC deficit
Funding
- Bundesamt fur Energie [SI/501614-01]
- Horizon 2020 Framework Programme
- Swiss State Secretary for Education, Research and Innovation (SERI) [17.00105]
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This study focuses on the modifications of the CIGS/Mo interface in Cu(In,Ga)Se-2 (CIGS) solar cells, leading to improvements in cell performance and carrier lifetime. The research shows that adjusting the back grading height effectively suppresses back interface recombination, emphasizing the importance of grading control for enhancing the performance of CIGS solar cells and devices.
The performance of Cu(In,Ga)Se-2 (CIGS) solar cells is limited by the presence of the highly recombinative CIGS/Mo interface. The recombination at the CIGS/Mo interface is influential for the open circuit voltage (V-OC) in high quality CIGS absorbers with increased charge carriers diffusion length. A quantitative understanding of the role of the Ga back grading height (Delta GGI) in suppressing back interface recombination is needed. In this work, we take advantage of a low temperature process to modify the Delta GGI while keeping the composition in the notch and front regions almost unchanged. Improvement in both V-OC deficit and time-resolved photoluminescence lifetime are observed with increasing Delta GGI. With a combination of back surface modification experiments and numerical simulations, we quantify a voltage loss in ungraded devices of approximately 100 mV solely from the back interface recombination. Nice agreement between simulation and experimental data is reached while constraining the values of possible diffusion lengths. Our results suggest that a Delta GGI of about 0.50 is required to effectively suppress the back interface recombination, highlighting the importance of grading control in high-performance CIGS solar cells and devices.
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