Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2016, Issue 31, Pages 5294-5300Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201600985
Keywords
Alkynes; Small-ring systems; Cyclization; Nitrogen heterocycles; Imines
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Cyclopropyl-tethered 3-alkynyl imines react with polarized-covalent-bond-containing compounds to give polyfunctionalized pyrroles. This provides a mild and effective method for the simultaneous introduction of halogen, chalcogen, or hydrogen groups to the 3-position of the pyrrole ring, together with the incorporation of halogen, azide, or alkoxy/aryloxy groups into the ethyl side-chain.
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