Journal
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
Volume 2016, Issue 25, Pages 4423-4428Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201600649
Keywords
Copper; Fluorine; Multiple bonds; Sulfur; Sulfoximines
Categories
Funding
- French Ministry of Research
- Universite de Versailles, St Quentin
- Vietnamese Government
- National Institute of Medicinal Materials in Hanoi
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The introduction of a double or triple bond to the nitrogen atom of S-perfluoroalkyl sulfoximines is described. We propose a simple catalytic system based on copper iodide for the reaction with bromoalkenes and bromoalkynes, and based on copper dichloride for the coupling with terminal alkynes. The fluorinated chain was varied from perfluorobutyl to monofluoromethyl. The reaction proceeds efficiently when the unsaturated system is substituted by an aryl or alkyl group. In particular, aliphatic terminal alkynes are efficient substrates for this transformation.
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