4.5 Article

Imidazolium zwitterion-based protic ionic liquids: from monomers to polymer membranes

Journal

POLYMER INTERNATIONAL
Volume 70, Issue 11, Pages 1582-1589

Publisher

WILEY
DOI: 10.1002/pi.6238

Keywords

polymerized ionic liquids; copolymerization; zwitterion; membranes; electrochemistry

Funding

  1. Russian Foundation for Basic Research [19-03-00505]
  2. Russian Science Foundation [16-13-10371]
  3. Russian Science Foundation [16-13-10371] Funding Source: Russian Science Foundation

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In this study, we investigated the thermal behavior, ion transport properties, and electrochemical stability of polymerized imidazolium-based protic ionic liquids (poly(ILs)) as potential materials for electrochemical devices. The phase behavior of both poly(ILs) and the corresponding IL monomers (MILS) was studied with differential scanning calorimetry and thermogravimetric analysis, and the temperature dependences of the conductivity and electrochemical window of all the MILS and poly(ILs) were discussed.
We present the results of synthesis and investigation of the thermal behavior, ion transport properties and electrochemical stability of polymerized imidazolium-based protic ionic liquids (poly(ILs)) as materials with potential applications in electrochemical devices. The phase behavior of both poly(ILs) and the corresponding IL monomers (MILS) was studied using differential scanning calorimetry and thermogravimetric analysis. The temperature dependences of the conductivity and electrochemical window of all the MILS and poly(ILs) are discussed. (C) 2021 Society of Chemical Industry

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