Journal
POLYHEDRON
Volume 204, Issue -, Pages -Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2021.115264
Keywords
Zinc; Hydride; N-donor ligand; Chelate; 3c, 2e bond
Categories
Funding
- Deutsche Forschungsgemeinschaft through the International Research Training Group Selectivity in Chemo-and Biocatalysis
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Selective protonolysis of polymeric zinc dihydride using the conjugate acid of TMPDA yielded stable molecular zinc hydride cations, with further reactions forming dimeric zinc hydride or dizinc trihydride cations.
Selective protonolysis of polymeric zinc dihydride [ZnH2](n) by the conjugate acid of the chelating N,N-donor TMPDA (TMPDA = N,N,N',N'-tetramethylpropane-1,3-diamine) [(TMPDA)H)][B(3,5-(CF3)(2)-C6H3)(4)] in THF gave the molecular zinc hydride cation [(TMPDA)ZnH(thf)][B(3,5-(CF3)(2)-C6H3)(4)] that is stable in THF but crystallized as the dimer [(TMPDA)(2)Zn-2(mu-H)(2)][B(3,5-(CF3)(2)-C6H3)(4)](2) from CH2Cl2/n-pentane. The protonolysis with half equivalent of the conjugate acid or the reaction of isolated [(TMPDA)ZnH (thf)][B(3,5-(CF3)(2)-C6H3)(4)] with one equivalent of zinc dihydride in THF gave the molecular dizinc trihydride cation [(TMPDA)(2)Zn2H2(mu-H)][B(3,5-(CF3)(2)-C6H3)(4)]. (C) 2021 Elsevier Ltd. All rights reserved.
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