Journal
ORGANIC LETTERS
Volume 23, Issue 10, Pages 3939-3943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01096
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Funding
- National Natural Science Foundation of China [21901118]
- Natural Science Foundation of Jiangsu Province [BK20190430]
- Fundamental Research Funds for the Central Universities [30919011217]
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A photoinduced oxidative alkoxycarbonylation of alkenes has been successfully demonstrated with alkyl formates as radical sources, providing a variety of alpha,beta-unsaturated esters with good regioselectivity and E selectivity under ambient conditions.
A photoinduced oxidative alkoxycarbonylation of alkenes initiated by intermolecular addition of alkoxycarbonyl radicals has been demonstrated. Employing alkyl formates as alkoxycarbonyl radical sources, a range of alpha,beta-unsaturated esters were obtained with good regioselectivity and E selectivity under ambient conditions.
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