Journal
ORGANIC LETTERS
Volume 23, Issue 10, Pages 3885-3890Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01016
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Funding
- National Natural Science Foundation of China [92056116, 21871194, 21971169, 21572142]
- National Key Research and Development Program of China [2017YFA0505903]
- Science & Technology Department of Sichuan Province [2019YJ0160, 2019YJ0090, 2017SZ0021]
- Fundamental Research Funds for the Central Universities [20826041D4117]
- Comprehensive Training Platform of Specialized Laboratory, College of Chemistry, Analytical & Testing Center, Sichuan University
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A bicyclic pillar[5]arene derivative fused with a bipyridine side ring, named a molecular universal joint (MUJ), was synthesized and the pair of enantiomers was resolved using high-performance liquid chromatography. The electrochemiluminescent detection based on the ruthenium complex of enantiopure MUJ demonstrated excellent chiral discrimination towards certain amino acids.
A bicyclic pillar[5]arene derivative fused with a bipyridine side ring, a so-called molecular universal joint (MUJ), was synthesized, and the pair of enantiomers was resolved by high-performance liquid chromatography enantioresolution. The electrochemiluminescent detection based on the ruthenium complex of the enantiopure MUJ showed excellent chiral discrimination toward certain amino acids.
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