4.8 Article

Acylation of Arenes with Aldehydes through Dual C-H Activations by Merging Photocatalysis and Palladium Catalysis

Journal

ORGANIC LETTERS
Volume 23, Issue 9, Pages 3772-3776

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01184

Keywords

-

Funding

  1. National Natural Science Foundation of China [21871228, 22061044]
  2. Program for Changjiang Scholars and Innovative Research Team in University [IRT_17R94]

Ask authors/readers for more resources

An acylation reaction of arenes with aldehydes through dual CH activations at room temperature was reported. The reaction was initiated by phenanthraquinone-catalyzed hydrogen atom transfer from aldehyde under visible light irradiation, followed by the merging of the aldehyde-derived acyl radical with palladium-catalyzed activation of arenes to afford the cross coupling products.
An acylation of arenes with aldehydes through dual CH activations at room temperature is reported. The acylation was initiated by phenanthraquinone-catalyzed hydrogen atom transfer from aldehyde under visible light irradiation. The aldehyde-derived acyl radical merged with palladium-catalyzed activation of arenes to afford the cross coupling products.

Authors

I am an author on this paper
Click your name to claim this paper and add it to your profile.

Reviews

Primary Rating

4.8
Not enough ratings

Secondary Ratings

Novelty
-
Significance
-
Scientific rigor
-
Rate this paper

Recommended

No Data Available
No Data Available