Journal
ORGANIC LETTERS
Volume 23, Issue 10, Pages 3960-3964Publisher
AMER CHEMICAL SOC
DOI: 10.1021/acs.orglett.1c01116
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- Leading Innovative and Entrepreneur Team Introduction Program of Zhejiang [2019R01005]
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This study established a selective and efficient synthesis of diaryl 1,3,5-oxadiazines for the first time from amidines in wet DMSO. The reaction involved the formation of two new C-N and two new C-O bonds, with DMSO acting as a dual carbon synthon and water providing the oxygen atom for constructing the oxadiazine ring.
A selective and efficient synthesis of diaryl 1,3,5-oxadiazines was established for the first time from simple and readily available amidines in wet DMSO. DMSO was employed as a dual carbon synthon and water offered the oxygen atom to construct the oxadiazine ring. The reaction involved two new C-N and two new C-O bond formations.
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