4.7 Article

Design a tunable glasses optical filters using CuO doped fluoroborate glasses

Journal

OPTICS AND LASER TECHNOLOGY
Volume 137, Issue -, Pages -

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.optlastec.2020.106829

Keywords

Borate glasses; CuO; Optical filters; Optical absorption

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A glass composition was successfully prepared using the melt quenching technique, with varying CuO ratios added to alter its optical properties, resulting in band-pass or cut-off glass filters. The changing CuO content influenced the optical absorption properties, with structures examined through FTIR absorption spectroscopy. The reasons for the filtering properties were discussed in relation to optical absorption, and the structural changes in the glass samples were analyzed using FTIR absorption spectroscopy.
Successfully, the glass composition (80% B2O3-15% NaF-5%CaF2) was prepared using the melt quenching technique. Different CuO ration from 0.3 wt% up to 12 wt% was added to the prepared glass composition at the expense of B2O3. The X-Ray diffraction pattern reveal the amorphous structure of the prepared glasses samples. The UV-Vis-NIR optical absorption spectrometer was used to investigate the optical properties of the glass samples. The structure was examined using the FTIR absorption spectroscopy. The optical absorption measurements reveal that the glasses sample from 0.30 wt% up to 3.60 wt% of CuO ratio produces band-pass glass filter samples. In addition, the CuO content of 6.0 wt% and higher concentrations up to 12.0 wt% give cut-off filters in the NIR region. The origin of the two types of filtering property was discussed in the frame of optical absorption and the changes in the glasses samples structure were discussed in the frame of FTIR absorption spectroscopy.

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