4.6 Article

Highly Efficient Ag3PO4/g-C3N4 Z-Scheme Photocatalyst for Its Enhanced Photocatalytic Performance in Degradation of Rhodamine B and Phenol

Journal

MOLECULES
Volume 26, Issue 7, Pages -

Publisher

MDPI
DOI: 10.3390/molecules26072062

Keywords

Ag3PO4; g-C3N4; semiconductor photocatalyst; Z-scheme mechanism

Funding

  1. National Natural Science Fund of China [51772099, 51872091]
  2. Scientific and Technological Research Projects of Colleges and Universities in Hebei Province [QN2019049]
  3. Postdoctoral Program of Hebei Province [B2020003015]
  4. Doctoral Initiation Fund [BS2017025]

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The Ag3PO4/g-C3N4 heterojunctions were synthesized using an in situ deposition method, and exhibited excellent photocatalytic degradation activity for Rh B and phenol under simulated sunlight conditions. The rapid charge separation between g-C3N4 and Ag3PO4 during the Z-scheme charge transfer and recombination process contributed to the significant improvement in photocatalytic activity and stability of g-C3N4/Ag3PO4.
Ag3PO4/g-C3N4 heterojunctions, with different g-C3N4 dosages, were synthesized using an in situ deposition method, and the photocatalytic performance of g-C3N4/Ag3PO4 heterojunctions was studied under simulated sunlight conditions. The results revealed that Ag3PO4/g-C3N4 exhibited excellent photocatalytic degradation activity for rhodamine B (Rh B) and phenol under the same light conditions. When the dosage of g-C3N4 was 30%, the degradation rate of Rh B at 9 min and phenol at 30 min was found to be 99.4% and 97.3%, respectively. After five cycles of the degradation experiment for Rh B, g-C3N4/Ag3PO4 still demonstrated stable photodegradation characteristics. The significant improvement in the photocatalytic activity and stability of g-C3N4/Ag3PO4 was attributed to the rapid charge separation between g-C3N4 and Ag3PO4 during the Z-scheme charge transfer and recombination process.

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