Tuning the Viscosity Profiles of High-Tg Poly(1,2,3-triazolium) Covalent Adaptable Networks by the Chemical Structure of the N-Substituents

A designed library of covalent adaptable networks (CANs) having 1,2,3-triazolium dynamic cross-links are obtained through the combination of solvent- and catalyst-free thermally induced azide-alkyne cycloaddition and N-alkylation reactions. The use of rigid heterocyclic or aromatic segments affords CANs with a greatly extended range of thermomechanical profiles, with T(g)s up to 146 degrees C, dramatic changes in relaxation times (from 1.5 h to less than 2 min at 150 degrees C) depending on the chemical structure of the N-substituents of 1,2,3-triazolium cross-links, and tunable rubbery plateaus, with nearly constant elastic moduli up to ca. 160 degrees C. A detailed correlation between the rheological properties and the chemical compositions of these CANs shows that the relaxation dynamics of the networks are mainly determined by the chemical structure of the N-substituents of the 1,2,3-triazolium cross-links and are independent of both the composition of the surrounding polymer networks and the corresponding T-g, at temperatures ranging from T-g + 20 degrees C up to T-g + 180 degrees C.

Automated summary

By combining thermally induced reactions, CANs with 1,2,3-triazolium dynamic cross-links were designed, offering a wide range of thermomechanical profiles achievable through modulation of chemical structure.