4.7 Article

Preliminary study on fire risk of redox flow battery components

Journal

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY
Volume 147, Issue 6, Pages 4131-4140

Publisher

SPRINGER
DOI: 10.1007/s10973-021-10815-1

Keywords

Redox flow battery; Fire risk; Components; Cone calorimeter; C80 calorimeter

Funding

  1. Science and Technology Project from China Southern Power Grid [020000KK52180010]

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The main fire hazard source of redox flow batteries is the electrode frame, followed by the bipolar plate. The thermal stability of membranes is the worst, while the electrode is a non-flammable component with little fire risk. These findings can provide safety guidelines for both improving RFBs and their large-scale usage.
The redox flow battery (RFB) is one new kind of energy storage unit, which is used in electrochemical energy storage. However, the knowledge on its fire risk is very limited. Thus the fire risk of redox flow batteries was investigated using cone calorimeter and C80 calorimeter in this work. The combustion behaviors of RFB components are tested using cone calorimeter, whereas the thermal behaviors of the component materials, including bipolar plate, electrode frame, electrode and membrane, inside the RFBs are measured using C80 calorimeter. By comparing the results in two experiments, it is indicated that the main hazardous source of the fire is the electrode frame, followed by the bipolar plate. The thermal stability of membranes is the worst. The electrode is a non-flammable component with little fire risk. This analytical results can provide safety guide for both improvements of RFBs and large scale usage.

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