Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 13-14, Pages 1967-1971Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201501195
Keywords
Metal-organic frameworks; Nanothermometers; Luminescence; Lanthanides; Nanostructures
Categories
Funding
- national funds through the Portuguese Fundacao para a Ciencia e a Tecnologia (FCT) [project CICECO Aveiro Institute of Materials] [FCT UID/CTM/50011/2013]
- national funds through the Portuguese Fundacao para a Ciencia e a Tecnologia (FCT) [SFRH/BPD/89003/2012, SFRH/BPD/95032/2013]
- Portuguese Ministerio da Educacao e Ciencia (MEC)
- Fundo Europeu de Desenvolvimento Regional (FEDER)
- Fundação para a Ciência e a Tecnologia [SFRH/BPD/89003/2012] Funding Source: FCT
Ask authors/readers for more resources
The microporous metal-organic framework MIL-103 doped with Tb3+ and Eu3+, formulated as [(Tb0.95Eu0.05)(btb)(H2O)](solv)(x) [H(3)btb = 1,3,5-tris(4-carboxyphenyl)benzene; solv = H2O, CH3OH] has been shown to be a good platform for luminescent ratiometric thermometry. Although operative over a wide range of temperatures (10-320 K), this material exhibits, in the cryogenic range (<100 K), one of the best performances of metal-organic frameworks, with a relative thermal sensitivity of 2.85%K-1 at 14 K. The material exists in the form of nanoparticles, suitable for nanothermometry applications (e.g., microfluidics). Moreover, as MIL-103 is nanoporous, its use as a multisensing platform deserves further consideration in the near future.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available