Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 1, Pages 35-38Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201601379
Keywords
Germanium; Lead; Low-valent compounds; Sandwich complexes; Tin
Categories
Funding
- Deutsche Forschungsgemeinschaft [SCHA-1915/3-1]
- Fonds der Chemischen Industrie
- Saarland University
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The concept of metallocenophanes has been well established for transition metals for a long time. Expanding this concept to p-block elements, the synthesis of sila[2] tetreloceno-phanes, with examples for germanium, tin, and lead as the central atoms, was explored. For the first time, the crystal structures of such compounds were obtained, and they gave intriguing insight into the geometry of this almost unexplored class of low-valent main-group molecules.
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