Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 12, Pages 1779-1783Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201501467
Keywords
Supramolecular chemistry; Photochemistry; Dihydrogen; Cobalt; Iridium
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Funding
- Fonds National pour la Recherche Scientifique (F.R.S.-FNRS), Belgium
- Fonds pour la Formation a la Recherche dans l'Industrie et dans l'Agriculture (F.R.I.A.), Belgium
- Region Wallonne, Belgium
- Universite Catholique de Louvain, Belgium
- Prix Pierre et Colette Bauchau, Belgium
- Natural Sciences and Engineering Research Council (NSERC), Canada
- Direction des Affaires Internationales de l'Universite de Montreal, Canada
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A bis-cyclometaling ligand afforded a novel Ir-III-Co-III dinuclear complex with vectorial electron transfer that evolved hydrogen gas upon yellow-light irradiation. The supramolecular photosystem provided increased stability during photocatalysis with respect to that of classic bidentate systems.
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