Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 27, Pages 4463-4469Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201600192
Keywords
Crystal growth; Metal-organic frameworks; Microporous materials; Nanotubes; Cobalt
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Funding
- Ministerio de Economia y Competitividad (MINECO) [ENE2014-56237-C4-4-R]
- Xunta de Galicia [GRC2014/042, Plan I2C]
- University of A Coruna (UDC)
- Barrie Foundation
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In this work, we have successfully synthesized hollow microtubular crystals of the metal organic framework (MOF) [Co-2(NH2-bdc)(2)(dabco)]center dot[G] {G = H2O, N,N-dimethylformamide (DMF); NH2-bdc =2-amino-1,4-benzenedicarboxylate; dabco = 1,4-diazabicyclo[2.2.2]octane} by a very simple coordination modulation method that avoids the use of an external modulator. Additionally, we have obtained the corresponding hollow microtubular crystals of Co3O4 through the solid-state thermolysis of the Co-MOF material at 400 degrees C. The as-prepared Co3O4 crystals exhibit the typical magnetic behavior for a nanostructured material with good crystallinity. Thus, this coordination modulation method provides a simple route for the preparation of nanostructured porous frameworks and derived oxides and opens a way to prepare new materials with advanced properties.
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