Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 11, Pages 1631-1634Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201600140
Keywords
Carbene ligands; Iridium; Charge transfer; Luminescence; Photophysics
Categories
Funding
- Centre National de la Recherche Scientifique (CNRS), Universite Pierre et Marie Curie (UPMC)
- Italian Ministry of Research [CX2TLM, RBFR10DAK6]
- Consiglio Nazionale delle Ricerche
Ask authors/readers for more resources
The synthesis of three deep-red-emitting iridium(III) complexes featuring a naphthalimide N-heterocyclic carbene ligand was investigated. The introduction of this organic chromophore onto the carbene moiety changed the character of the lowest excited state from triplet metal-to-ligand charge transfer to triplet ligand centered, as corroborated by time-dependent DFT calculations. All complexes displayed a naphthalimide- based deep-red phosphorescence emission above lambda = 630 nm in polymer matrix with good quantum yields (Phi approximate to 0.2) and long lifetimes.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available