Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 34, Pages 5324-5331Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201600782
Keywords
Electron transfer; Magnetic properties; Moessbauer spectroscopy; Iron; Cobalt; Polarizability
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Funding
- Scopes project [IZ73Z0_152404]
- Supreme Council for Science and Technological Development of the Republic of Moldova [15.817.02.06F]
- Swiss National Science Foundation (SNF) [IZ73Z0_152404] Funding Source: Swiss National Science Foundation (SNF)
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We present a new microscopic approach for the description of the effects of an external direct current (dc) electric field on the magnetic, polarizability, and spectroscopic characteristics of molecular crystals containing cyanide-bridged Fe-Co clusters as structural units. In addition to the interaction with the electric field, the model allows for metal-metal electron transfer, intracluster magnetic exchange, and long-range electron-deformational interactions, which are taken into account within the mean-field approach. The external electric field gives a unique possibility to manipulate the polarizability, magnetic, and spectroscopic characteristics of cyanide-bridged Fe-Co clusters.
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