Correlating Charge-Transfer State Lifetimes with Material Energetics in Polymer:Non-Fullerene Acceptor Organic Solar Cells

Minimizing the energy offset between the lowest exciton and charge-transfer (CT) states is a widely employed strategy to suppress the energy loss (E-g/q - V-OC) in polymer:non-fullerene acceptor (NFA) organic solar cells (OSCs). In this work, transient absorption spectroscopy is employed to determine CT state lifetimes in a series of low energy loss polymer:NFA blends. The CT state lifetime is observed to show an inverse energy gap law dependence and decreases as the energy loss is reduced. This behavior is assigned to increased mixing/hybridization between these CT states and shorter-lived singlet excitons of the lower gap component as the energy offset Delta ECT-S1 is reduced. This study highlights how achieving longer exciton and CT state lifetimes has the potential for further enhancement of OSC efficiencies.

Automated summary

Reducing the energy offset between the lowest exciton and charge-transfer states can suppress energy loss in polymer:NFA organic solar cells. The study found that as the energy loss decreases, the CT state lifetime decreases as well, indicating increased mixing and hybridization between CT states and shorter-lived singlet excitons. Achieving longer exciton and CT state lifetimes has the potential to enhance OSC efficiencies.