Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 143, Issue 19, Pages 7247-7252Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.1c01967
Keywords
-
Categories
Funding
- NIGMS [R35 GM127135]
Ask authors/readers for more resources
A method for acetoxyhydroxylation of olefins with syn stereoselectivity under electrophotocatalytic conditions using a TAC ion catalyst has been developed. The reaction, catalyzed by visible light irradiation at controlled electrochemical potential, converts aryl olefins to glycol monoesters with high chemo- and diastereoselectivity. It can be carried out in batch or flow, enabling the synthesis of multigram quantities of the monoester products.
A method for the acetoxyhydroxylation of olefins with syn stereoselectivity under electrophotocatalytic conditions is described. The procedure uses a trisaminocyclopropenium (TAC) ion catalyst with visible light irradiation under a controlled electrochemical potential to convert aryl olefins to the corresponding glycol monoesters with high chemo- and diastereoselectivity. This reaction can be performed in batch or in flow, enabling multigram synthesis of the monoester products.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available