Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 15-16, Pages 2349-2356Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201501326
Keywords
Tripodal ligands; Scorpionate ligands; Dinitrogen ligans; Dioxygen ligands; N ligands
Categories
Funding
- US Department of Energy [DE-FG02-92ER14273]
- U.S. Department of Energy (DOE) [DE-FG02-92ER14273] Funding Source: U.S. Department of Energy (DOE)
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Dinitrogen complexes of the first row transition metals Cr-Co supported by 2(nd) generation hydrotris(pyrazolyl)borate (Tp(R,R)) ligands were characterized by structure and reactivity. Compounds of the type (Tp(R,R)M)(n)(N-2) (n = 1,2) were prepared and evaluated as precursors for small molecule activation, with specific application to reactions of O-2.
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