Journal
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
Volume -, Issue 15-16, Pages 2296-2311Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201501470
Keywords
Scorpionate ligands; C-H activation; Olefin hydroarylation; Homogeneous catalysis
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Funding
- Office of Basic Energy Science, U.S. Department of Energy [DE-SC0000776, DE-FG02-03ER15387]
- U.S. National Science Foundation (NSF) [CHE-1465145]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1465145] Funding Source: National Science Foundation
- U.S. Department of Energy (DOE) [DE-SC0000776] Funding Source: U.S. Department of Energy (DOE)
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The emergence of hydridotris(pyrazolyl)borate (Tp) and related ligands has had a substantial influence in the field of organometallic chemistry with regards to C-H activation. The electronic and structural properties of Tp and related ligands, such as poly(pyrazolyl)alkane ligands, play an important role in the ability of several transition metal complexes to mediate C-H activation and functionalization. Herein, several studies of stoichiometric and catalytic C-H activation by platinum group metals are reviewed.
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