4.5 Article

Hierarchical highly porous composite ceramic material modified by hydrophobic methyltrimetoxysilane-based aerogel

Journal

JOURNAL OF POROUS MATERIALS
Volume 28, Issue 4, Pages 1237-1244

Publisher

SPRINGER
DOI: 10.1007/s10934-021-01075-3

Keywords

Methyltrimethoxysilane; Composite material; SiO2; Hydrophobicity; Aerogel

Funding

  1. Russian Foundation for Basic Research [18-29-06014]
  2. IPAC RAS Joint Research Centre [0090-2019-0002]

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The composite material exhibits high hydrophobic properties and low water absorption, while maintaining mechanical integrity after multiple freeze-thaw cycles.
A highly porous composite material consisting of silicon dioxide microfibers filled with nanoporous methyltrimethoxysilane-based aerogel was synthesized by a sol-gel procedure followed by supercritical drying in isopropanol and CO2. The textural and mechanical properties of the composite were studied. A synergism of the mechanical properties of components was demonstrated. The material showed high hydrophobic properties-the water drop contact angle was 142 degrees after 14 days under 100% humidity and low water absorption was found. The composite material retained its mechanical integrity after several freeze-thaw procedures.

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