Journal
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY
Volume 413, Issue -, Pages -Publisher
ELSEVIER SCIENCE SA
DOI: 10.1016/j.jphotochem.2021.113185
Keywords
Phthalimides; isoindolin-1-ones; Isoindolines; Fluorescence; Absorption and emission
Categories
Funding
- CONACYT of Mexico [286614]
- CONACYT [388503]
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Both experimental and theoretical methods were used to study the fluorescent properties of nine new compounds based on phthalimides, isoindolin-1-ones and isoindolines bearing aminobenzoic acids. The compounds showed fluorescence emission and high quantum yields in methanol solutions. The intramolecular charge in these donor-acceptor systems was found to significantly depend on electron-withdrawing substituents at the carboxylic acid position.
Both experimental and theoretical methods were used in order to study the fluorescent properties of nine new compounds based on phthalimides, isoindolin-1-ones and isoindolines bearing aminobenzoic acids (2-aminobenzoic acid, 3-aminobenzoic acid and 4-aminobenzoic acid), which were obtained under mild reaction conditions. The photophysical properties of all the compounds were studied by electronic absorption and fluorescence spectroscopy in methanol solutions. All compounds exhibited fluorescence emission and high quantum yields. Additionally, it was found that the intramolecular charge in these donor-acceptor systems is significantly depending on electron-withdrawing substituents at the carboxylic acid position.
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