4.6 Article

Synthesis and characterization of physicochemical properties of imidazolium-based ionic liquids and their application for simultaneous determination of sulfur compounds

Journal

JOURNAL OF MOLECULAR STRUCTURE
Volume 1230, Issue -, Pages -

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ELSEVIER
DOI: 10.1016/j.molstruc.2021.129917

Keywords

Imidazolium-based ionic liquids; Physicochemical properties; Temperature-Dependence; Scavengers

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Synthesized and characterized three types of IMILs through various analytical techniques. Physicochemical properties of IMILs were found to be temperature-dependent, decreasing with increasing temperature. Electrochemical studies demonstrated potential applications of IMILs in screen-printed electrode cells for modern applications.
Three types of imidazolium-based ionic liquids (IMILs) were synthesized and characterized by C-13 and H-1 NMR, FT-IR, and elemental analysis. Thermal stability and physicochemical properties of prepared IMILs were measured in the temperature range of 283.15 to 363.15 K. The physicochemical results revealed the entirely temperature-dependent properties and quietly decreasing through increasing the temperature. Electrochemical studies of the IMILs were also performed at the surface of screen-printed electrode cells. Consideration of these properties and determining the unique abilities of IMILs will help researchers through modern applications like liquid-liquid extraction, particular tasks of scavenging and removal of hydrogen sulfide and thiols from petroleum matrices. (C) 2021 Elsevier B.V. All rights reserved.

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