The effects of phosphorus-free inhibitors on the ignition of lycopodium dust

The minimum ignition temperature of dust suspension (MIT) and the hot surface ignition temperature of the dust layer (LIT) are essential safety parameters for the process industry. However, the knowledge of the ignition behavior when solid mixtures of flammable fuels and phosphorous-free inhibitors are considered is still scarce and further experimental and theoretical analyses are requested. In this work, the ignition temperature of phosphorous-free inhibitors (coal fly ash and calcium carbonate) mixed with lycopodium dust have been studied in terms of LIT analysis (hot plate thickness: 5 mm, 12.5 mm and 15 mm), and by the Godbert-Greenwald test for the MIT. Both coal fly ash and calcium carbonate have been tested at different concentrations and particle sizes. Results show that the effects of the inhibitor can be counter-productive when layer ignition temperature is considered even if the minimum ignition temperature of the dust suspension shows a positive effect from the safety point of view. This behavior has been analyzed in the terms of thermal conductivity and diffusivity of the mixture, by using Maxwell's equation for two-phase solid mixtures. Standard empirical correlations for the ignition temperature of solid mixtures have been also tested, showing their weakness in reproducing mixture behavior.

Automated summary

The ignition behavior of solid mixtures containing flammable fuels and phosphorus-free inhibitors requires further experimental and theoretical analyses to understand their effects on ignition temperatures. Inhibitors may have counter-productive effects on layer ignition temperature, despite showing positive effects on the minimum ignition temperature of dust suspension. The thermal properties of the mixture, analyzed using Maxwell's equation, and the weaknesses of standard empirical correlations for predicting ignition temperature of solid mixtures were investigated.