Journal
JOURNAL OF COLLOID AND INTERFACE SCIENCE
Volume 601, Issue -, Pages 793-802Publisher
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2021.05.095
Keywords
Supercapacitor; Energy density; Hierarchical structure; Energy storage; Rate capacitance
Categories
Funding
- Jiangsu Province Postdoctoral Science Foundation [2020Z247]
- China Postdoctoral Science Foundation [2020M681519]
- Innovation Entrepreneurship Pro-gram of Jiangsu Province [[2016] 32]
- National Natural Science Foundation of China [21878129]
- Industry Pro-spect and Key Core Technology (Competition Project) of Jiangsu Province [BE2019093]
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In this study, P-doped NiCo2O4/NiMoO4 multi-dimensional nanostructures were successfully synthesized as electrode materials for supercapacitors, exhibiting high specific capacitance at low current density and excellent cycle stability at high current density. A hybrid supercapacitor device was prepared with high energy density at low power density, and showed excellent capacity retention rate after a large number of cycles, demonstrating the huge potential of multi-dimensional metal oxides in energy storage.
Multi-dimensional metal oxides have become a promising alternative electrode material for supercapacitors due to their inherent large surface area. Herein, P-doped NiCo2O4/NiMoO4 multi-dimensional nanostructures are synthesized on carbon clothes (CC) with a continuous multistep strategy. Especially, P has the best synergistic effect with transition metals, such as optimal deprotonation energy and OH- adsorption energy, which can further enhance electrochemical reaction activity. For the above reasons, the P-NiCo2O4/NiMoO4@CC electrode exhibits an ultra-high specific capacitance of 2334.0 F g(-1) at 1 A g(-1). After 1500 cycles at a current density of 10 A g(-1), its specific capacity still maintains 93.7%. Besides, a P-NiCo2O4/NiMoO4@CC//activated carbon device (hybrid supercapacitor or device) was also prepared with a maximum energy density of 45.1 Wh kg(-1) at a power density of 800 Wkg(-1). In particular, the capacity retention rate is still 89.97% after 8000 cycles due to its excellent structural stability. Our work demonstrates the vast potential of multi-dimensional metal oxides in energy storage. (C) 2021 Published by Elsevier Inc.
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